A Moment of Science

Why Is Dry Ice Dry?

If you've ever received a special shipment of meat or seafood at home, it probably arrived surrounded by blocks of dry ice. What is dry ice?

dry ice in blue bucket

Photo: Mr.Thomas (flickr)

Using dry ice can be a safe and effective way to ship something that needs to be cold.

If you’ve ever received a special shipment of meat or seafood at home, it probably arrived surrounded by blocks of dry ice.

When you place the blocks in your sink, they slowly disappear, but no water streams from the sides as you’d expect from melting ice. How does dry ice perform this disappearing act? Why is dry ice dry?

Sublimation

The secret is in the chemical composition of dry ice, which is carbon dioxide in solid form. At room temperature, carbon dioxide exists as a gas–the very gas we exhale every time we breath. But this familiar compound has some unusual physical properties.

Instead of melting at room temperature into a liquid, and then evaporating into gas, dry ice passes directly from solid to gas by a process called sublimation.

Reverse Process

So that disappearing block actually sublimates into the air as colorless carbon dioxide gas. The reverse process can also occur–at extremely cold temperatures, carbon dioxide gas changes directly into a solid.

So does carbon dioxide ever exist as a liquid? In other words, is dry ice always dry? Carbon dioxide does have a liquid form–in fact, it’s stored as a liquid in tanks for the manufacture of dry ice.

Decreasing Pressure

But changing into a liquid is one trick the compound won’t perform in your kitchen sink. At room temperature, the only way to bring carbon dioxide to a liquid state is to drastically increase the pressure, to at least about fifty-five times normal atmospheric pressure. So that’s why dry ice–under everyday household conditions–is dry.

  • http://twitter.com/dryicenetwork Rob

    This is very good information.  Why is dry ice dry is actually a common question by people.  I think you did a great job explaining it.  One thing to note is that if you place dry ice in a sealed test tube, it can build up enough pressure to turn to liquid.  Again, great job.

    DryIceNetwork.com

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